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silverprotein

  • 中文别名:弱蛋白银
  • 中文释义:组织用蛋白银;弱蛋白银
  • 英文别名:Silver Proteinate;
    SILVER 
  • cas No.:9015-51-4
  • 分子式:

    Ag

  • 分子量:107.87
  • 精确分子量:106.90500
  • PSA:0.00000
  • 分子结构式:

物化性质

外观与性状:
暗棕色有光泽的晶体
密度:
1.135 g/mL at 25 °C
熔点:
960 °C(lit.)
沸点:
2212 °C(lit.)
闪点:
232 °F
折射率:
n20/D 1.333
蒸汽密度:
5.8 (vs air)
存储条件/存储方法:

充氩密封干燥避光保存。

稳定性相关:

遵照规定使用和储存则不会分解。

其它信息:

1. 性状:商品按含银量不同可分为强、弱蛋白银。强蛋白银含银8%,浅黄橙色至棕黑色无气味的鳞片和颗粒。

安全信息

外观与性状:
暗棕色有光泽的晶体
密度:
1.135 g/mL at 25 °C
熔点:
960 °C(lit.)
沸点:
2212 °C(lit.)
闪点:
232 °F
折射率:
n20/D 1.333
蒸汽密度:
5.8 (vs air)
存储条件/存储方法:

充氩密封干燥避光保存。

稳定性相关:

遵照规定使用和储存则不会分解。

其它信息:

1. 性状:商品按含银量不同可分为强、弱蛋白银。强蛋白银含银8%,浅黄橙色至棕黑色无气味的鳞片和颗粒。

毒理性

毒理学数据:

有毒,有刺激性

生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

MSDS

Section 1. Chemical Product and Company Identification
Silver Protein, mild
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
Silver Protein, mild
Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention.
Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.
InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious InhalationNot available.
IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious IngestionNot available.
Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flash PointsNot available.
Flammable LimitsNot available.
Products of CombustionNot available.
Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
Various SubstancesNon-flammable in presence of shocks.
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available.
Fire Fighting MediaSMALL FIRE: Use DRY chemical powder.
and InstructionsLARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks onNot available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not
present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Silver Protein, mild
Section 7. Handling and Storage
PrecautionsKeep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the
residue under a fume hood. Ground all equipment containing material. Do not breathe dust. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek
medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away from
incompatibles such as acids.
StorageHygroscopic. Light sensitive. Store light-resistant container. Keep container tightly closed. Keep container in a
cool, well-ventilated area. Do not store above 24°C (75.2°F).
Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
TWA: 0.01 (mg(Ag)/m3) from ACGIH (TLV) [United States]
Exposure Limits
TWA: 0.01 (mg(Ag)/m3) from OSHA (PEL) [United States]
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Crystalline solid.)Odorless.
Odor
TasteNot available.
Molecular WeightNot available.
ColorBrown. Almost black (Dark.)
pH (1% soln/water)Not available.
Not available.
Boiling Point
Melting PointDecomposes.
Critical TemperatureNot available.
Not available.
Specific Gravity
Vapor PressureNot applicable.
Not available.
Vapor Density
VolatilityNot available.
Not available.
Odor Threshold
Water/Oil Dist. Coeff.Not available.
Ionicity (in Water)Not available.
Dispersion PropertiesSee solubility in water.
SolubilitySoluble in cold water, hot water.
Silver Protein, mild
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Instability TemperatureNot available.
Excess heat, incompatible materials
Conditions of Instability
Reactive with acids.
Incompatibility with various
substances
CorrosivityNot available.
Special Remarks onHygroscopic. Light Sensitve. Decomposes on exposure to light.
ReactivityAlso incompatible with neutral and acid salts in concentrated solutions.
Special Remarks onNot available.
Corrosivity
PolymerizationWill not occur.
Section 11. Toxicological Information
Routes of EntryInhalation. Ingestion.
Toxicity to AnimalsLD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects onHazardous in case of skin contact (irritant), of ingestion, of inhalation.
Humans
Special Remarks onNot available.
Toxicity to Animals
Special Remarks onMay cause cancer based on animal data. However, at the timeof this review, no studies were found on the
Chronic Effects on Humanspossible carcinogenic activity of silver compounds in humans.
Special Remarks on otherAcute Potential Health Effects:
Toxic Effects on HumansSkin: May cause skin irritation.
Eyes: May cause mechanical eye irritation.
Inhalation: May cause respiratory tract irritation. Expoures above TLV may result in acculmulation of silver in the
body (argyria) Symptoms may include a permanent blue-gray pigmentation of the skin, mucous membranes, and
eyes.
Ingestion: May be harmful if swallowed. large doses may result in silver poisong, which may show symptoms of
gastroenteritis (gastrointestinal tract irritation), spasms, and skin discoloration.
Prolonged or repeated inhalation, application, or ingestion of silver compounds may cause a permanent bluish
discoloration of the skin and mucous membranes, and may also affect blood, and liver.
Section 12. Ecological Information
EcotoxicityNot available.
BOD5 and CODNot available.
Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the ProductsNot available.
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Silver Protein, mild
Section 13. Disposal Considerations
Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental
control regulations.
Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
Not applicable.
Identification
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
No products were found.
Federal and State
Regulations
California
Proposition 65
Warnings
Other RegulationsNot available.
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
DSCL (EEC)R36/38- Irritating to eyes and skin.S2- Keep out of the reach of children.
S46- If swallowed, seek medical advice
immediately and show this container or label.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
1 Flammability
1 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
Silver Protein, mild
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.
SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用

2、 摩尔体积(cm3/mol):无可用

3、 等张比容(90.2K):无可用

4、 表面张力(dyne/cm):无可用

5、 极化率:无可用

计算化学数据

1、 疏水参数计算参考值(XlogP):1.3

2、 氢键供体数量:1

3、 氢键受体数量:2

4、 可旋转化学键数量:1

5、 拓扑分子极性表面积(TPSA):29.5

6、 重原子数量:9

7、 表面电荷:0

8、 复杂度:75

9、 同位素原子数量:0

10、 确定原子立构中心数量:0

11、 不确定原子立构中心数量:0

12、 确定化学键立构中心数量:0

13、 不确定化学键立构中心数量:0

14、 共价键单元数量:1

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